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Drop-Scale Transport Processes of Acid Rain

The chemical reactions described earlier must be considered together with the transport processes to obtain a quantitative picture of acid rain formation. This is especially true for S02 because absorption and reactions occur simultaneously. The convective transport influences the concentrations of different species and hence the reaction rates. Figure 2.2 illustrates these processes schematically. These include the following.

External Transport

This refers to the transport of S02 gas toward the surface of the drop. It is a convective diffusion process (both convective transport and diffusional transport occur) and is influenced by the flow fields created by the falling drop and atmospheric conditions (pressure and temperature).

Interfacial Transport

Once SO, is adsorbed on the surface of the drop, it must be transferred into the interior for further reactions to occur. The time for establishing phase equilibrium is controlled by Henry’s law constant and mass accommodation coefficient of SO,.

A schematic of the drop-scale transport process of sulfur species involved in the acid rain. Internal Transport

FIGURE 2.2 A schematic of the drop-scale transport process of sulfur species involved in the acid rain. Internal Transport

In the interior of the drop, reactions121 occur. At the same time, these species are transported by both diffusion and internal circulation. The latter is caused by the motion of the liquid drop in a viscous medium and can influence the production rates of these species (see Pruppacher and Klett11)).

Environmental Factors Influencing the Acid Rain Formation and Impacts

Like many environmental hazards, the acid rain process is not driven by a few well-controlled physical and chemical processes, but involves complicated interactions between the chemicals and the environments they exist in. While the main ingredients of acid rain come from industrial activities, many other factors may influence the formation of acid rain and its impacts. The following are some of the most important.

Meteorological Factors

Acid rain occurs in the atmosphere and hence is greatly influenced by meteorological factors such as wind direction and speed, amount and frequency of precipitation, pressure patterns, and temperature. For example, in drier climates, such as the western United States, wind-blown alkaline dust is abundant and tends to neutralize the acidity in the rain. This is the buffering effect of the dust. In humid climates, like the Eastern Seaboard, less dust is in the air, and precipitation tends to be more acidic.

Seasonality may also influence acid precipitation. For example, while it is true that rain may be more acidic in summer (because of higher demands for energy and hence more fossil fuel used), the snow in winter can also pick up a substantial amount of acids. These snow-borne acids can accumulate throughout winter (if the weather is cold enough) and then are released in large doses during the spring thaw. These large doses of acid may have more significant effects during fish spawning or seed germination than the same doses at some less critical time.

Topography and Geology

The topography and geology of an area have marked influence on acid rain effects. Research from the U.S. EPA pointed out that areas most sensitive to acid precipitation are those with hard, crystalline bedrock and very thin surface soils. Here, in the absence of buffering properties of soil, acid rains will have direct access to surface waters and their delicate ecosystem. Areas with steep topography, such as mountainous areas, generally have thin surface soils and hence are very vulnerable to acid rain. In contrast, a thick soil mantle or one with high buffering capacity, such as most flatlands, helps keep acid rain damage down.

The location of water bodies is also important. Headwater lakes and streams are especially vulnerable to acidification. Lake depth, the ratio of water-shed area to lake area, and the residence time in lakes all play a part in determining the consequent threat posed by acids. The transport mode of the acid (rains or runoff) also influences the effects.

Biota

Acid rain may fall on trees causing damages. The kinds of trees and plants in an area, their heights, and whether they are deciduous or evergreen may all play a part in the potential effects of acid rain. Without a dense leaf canopy, more acid may reach the Earth to impact on soil and water chemistries. Stresses on the plants will also affect the balance of local ecosystem. Additionally, the rate at which different types of plants carry on their normal life processes influences an area’s ratio of precipitation to evaporation. In locales with high evaporation rates, acids will concentrate on leaf surfaces. Another factor is that leaf litter decomposition may add to the acidity of the soil due to normal biological actions.

References

  • 1. Pruppacher, H.R.; Klett, J.D. Microphysics of Clouds and Precipitation; Kluwer Academic Publishers: 1997; 954 pp.
  • 2. Seinfeld, J.H.; Pandis, S.N. Atmospheric Chemistry and Physics; John Wiley and Sons: 1998.

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