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Membrane Desalination: From Nanoscale to Real World Applications
DESALINATION NECESSITY
DESALINATION PROCESSES
Thermal Desalination Processes
Distillation
Multistage Flash (MSF)
Multieffect Distillation (MED)
Vapor Compression (VC)
Membrane Desalination
Reverse Osmosis (RO)
Forward Osmosis (FO)
Electrodialysis (ED)
Membrane Distillation (MD)
MEMBRANE PREPARATION TECHNIQUES
Thin Film Composite (TFC)
DESALINATION MEMBRANE SHAPES AND MODULES
Tubular Modules
Spiral-Wound Modules
Hollow-Fiber Modules
Pretreatment
REFERENCES
Membrane Materials Design Trends: Nanoadditives
INTRODUCTION
Hydrophilicity
Fouling
Porosity
Permeability
Rejection
Roughness
Mechanical Properties
GRAPHENE OXIDE NANOADDITIVES
Preparation
Effect on Morphology
Effect on Performance
Effect on Mechanical Properties
CARBON NANOTUBE (CNTS) ADDITIVES
Preparation
Effect on Morphology
Effect on Performance
Effect on Mechanical Properties
Mechanism of Action
ZEOLITE NANOADDITIVES
Zeolite Preparation
Effect on Water Permeability and Hydrophilicity
Fouling
Effect on Morphology
Effect on Mechanical Properties
SILICA NANOPARTICLES
Preparation of Functionalized Silica
Effect on Mechanical Properties
Effect on Morphology
Effect on Performance
Mechanism of Action
METAL OXIDES NANOPARTICLES
Preparation
Coprecipitation Method
Sol-Gel Method
Thermal Decomposition
Microemulsion Process
Effect on Mechanicaf Properties
Effect on Performance and Hydrophilicity
Effect on Morphology
METAL SALT NPS
Silver NPs
Preparation
Effect of Silver NPs on Membrane Characteristics and Performance
Copper (Cu) NPs
NANOCELLULOSE ADDITIVE
Preparation
Effect on Mechanicaf Properties
Effect on Morphology
Effect on Performance
OTHER NPS
Preparation of Polyaniline (PANI)
Chemical Synthesis (Oxidative Polymerization)
Electrochemical Synthesis
Effect on Morphology
Characteristics and Performance
ACKNOWLEDGEMENT
REFERENCES
Functionalization of Carbon-Based Additives
INTRODUCTION
GRAPHENE-BASED ADDITIVES
CARBON NANOTUBE - BASED ADDITIVES
REFERENCES
Nanohybrid Graphene-Based Materials for Advanced Wastewater Treatment: Adsorption and Membrane Technology
INTRODUCTION
SYNTHESIS PROCEDURES
Synthesis of GO
Nanohybrid GO
Preparation of GO and Reduced GO (rGO) Mixture
Synthesis of Fe3О4/rG0
Preparation of GO with One-step Ultrasonication
Synthesis of Magnetic Chitosan Functionalized with GO
CHARACTERIZATIONS
PREPARATION METHODS OF GO MEMBRANES
Filtration-Assisted Method
Casting/Coating-Assisted Method
Layer-by-Layer Assembly Method
Other Methods
ADSORPTION APPLICATION OF NANOHYBRID GO
Adsorption Isotherms
Examples
Applications of Nanohybrid GO Membranes
CONCLUSIONS
REFERENCES
State of the Art and Perspectives in Membranes for Membrane Distillation/Membrane Crystallization
INTRODUCTION TO MEMBRANE DISTILLATION (MD) AND MEMBRANE CRYSTALLIZATION (MCr) TECHNOLOGIES
PRINCIPLES OF MD TECHNOLOGY
Transport Mechanisms in MD
Heat Transfer in MD
Mass Transfer in MD
PRINCIPLES OF MCr TECHNOLOGY
FROM LABORATORY STUDIES TO LARGE-SCALE APPLICATIONS
ADVANTAGES AND STILL EXISTING LIMITATIONS
Membranes for MD and MCr
Membranes Materials: Traditional and Emerging
Membrane Configurations and Membrane Modules
Membrane Fabrication Techniques
Advances in Membrane Fabrication and Modification
Environmental Issues in Membrane Fabrication
An Overview of Commercially Available Membranes Used in MD
Conclusions and Perspectives
ACKNOWLEDGEMENT
REFERENCES
Artificial Water Channels: Toward Next-Generation Reverse Osmosis Membranes
INTRODUCTION
NATURAL WATER CHANNELS -THE AQUAPORINS
BIOASSISTED AQP-EMBEDDED MEMBRANES
WHY ARE ARTIFICIAL WATER CHANNELS IMPORTANT?
WHERE ARE WE NOW? WHERE ARE WE GOING IN THIS NEWBORN FIELD?
Single Molecular Channels
Self-assembled Supramolecular Channels
Nanochannels
OUTLINE BEYOND STATE OF ART
CONCLUSIONS
REFERENCES
Desalination Membranes: Characterization Techniques
INTRODUCTION
MEMBRANE CHARACTERIZATION
Surface Morphology and Physical Characteristics
Porous Structure Characterization
Electron Microscopy
SEM
Transmission Electron Microscopy (ТЕМ)
Atomic Force Microscopy (AFM)
Fourier-Transform Infrared (FTIR) Microscopy
Surface Chemical Characteristics
Energy Dispersive X-ray Spectroscopy (EDX)
X-ray Photoelectron Spectroscopy (XPS)
Attenuated Total Reflectance - Fourier-Transform Infrared (ATR-FTIR)
X-ray Powder Diffraction (XRD)
Water Contact Angle
Zeta Potential Measurement Surface Charge
Thermal and Mechanical Properties
Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC)
Tensile Strength Test
MEMBRANE PERFORMANCE
Permeation Flux
Membrane Liquid Entry Pressure of Water (LEPw)
Salt Reiection Rate
CONCLUSIONS
REFERENCES
Carbon Molecular Models for Desalination
INTRODUCTION
EXISTING MODELS
Graphene and Graphene Oxide (GO)
Carbon Nanotube (CNT)
Biomimetic
CONCLUSIONS
REFERENCES
Virtual Material Design: A Powerful Tool for the Development of High-Efficiency Porous Media
CHARACTERIZATION OF MEMBRANE STRUCTURE
COMPUTATIONAL FLUID DYNAMICS IN POROUS MEDIA
VIRTUAL MATERIAL DESIGN (VMD)
SYNTHETIC MEMBRANE STRUCTURES
VMD AND CFD SIMULATIONS
CONCLUSIONS
REFERENCES
Estimation of Process Parameters in Industrial Membrane Manufacture Using Computational Fluid Dynamics
INTRODUCTION
INVESTIGATION OF LIQUID - LIQUID DEMIXING IN POLYMER SOLUTIONS AND MICROSTRUCTURE EVOLUTION
NUMERICAL PREDICTION OF HEAT AND MASS TRANSFER IN CASTING MACHINES
MODELING OF PHASE SEPARATION
CONCLUSIONS
REFERENCES
Towards Energy-Efficient Reverse Osmosis
INTRODUCTION
ENERGY CONSUMPTION OF RO PLANTS
Energy Breakdown
Intake Systems
Pretreatment
Product Water Delivery
Other Processes and Services
RO System
RO MEMBRANES AND PLANT ENERGY CONSUMPTION
Thin-Film Composite Membranes
Nanocomposite Membranes
Emerging Membrane Types
Membrane Fouling
CONFIGURATIONS OF RO SYSTEM TO MINIMIZE SEC
Multistage RO Systems
Multipass RO Systems
Split-Partial Two-Pass Systems
Hybrid Membrane Configuration
Time-Varying Pressure Systems - Batch RO Systems
PUMPS
High Flow Capacity Centrifugal Pumps
Positive Displacement Pumps
ENERGY RECOVERY DEVICES
SUMMARY AND CONCLUSIONS
REFERENCES
Membrane Fouling and Scaling in Reverse Osmosis
INTRODUCTION
EFFECT OF FOULING AND SCALING
Increasing Differential Pressure in Cross - Wound Fibers, or of Spacer Spiral Wound Elements
Increase Hydraulic Resistance of the Membrane
Decrease in Rejection Owing to Concentration Polarization in the Foul Layer
FOULING TYPES
Particulate Fouling
Silt Density Index (SDI)
Modified Fouling Index (MFI0.45)
Modified Fouling Index (MFI - UF)
MFI-UF at Constant Flux
Transparent Exopolymer Particles (TEPs)
Biological Fouling
Monitoring the Biofilm Development
Monitoring Biofouling Potential
Assimilable Organic Carbon (AOC)
Biodegradable Dissolved Organic Carbon (BDOC)
Bacterial Growth Potential (BGP)
Performance Restoration
Organic fouling
Scaling in Reverse Osmosis Systems
Scaling Compounds on the RO Membranes
Calcium Carbonate Scaling
Calcium Sulphate Scaling
Barium Sulphate Scaling
Calcium Phosphate Scaling
Mechanism of Scaling in Reverse Osmosis
Prediction of Scaling
Scaling Indices
Scaling Prediction with Computer Software
Techniques to Control Scaling
Addition of Scale Inhibitors
Operate at Low Recovery
Acid addition
REFERENCES
Sustainable Development and Future Trends in Desalination Technology
INTRODUCTION
FLEXIBLE INFRASTRUCTURE PLANNING AND SUSTAINABLE DEVELOPMENT
MANAGEMENT AND TREATMENT OF HYPERSALINE BRINE SOLUTIONS THROUGH USE OF LOW GRADE HEAT AND SOLVENT EXTRACTION
EFFECTS OF BRINE DISCHARGE AND METERING TRENDS ON DESALINATION PLANT CONSTRUCTION
ENERGY EFFICIENCY, COST ANALYSIS, AND ROAD MAP TO SUSTAINABLE DESALINATION
COMPARISON OF ENERGY CONSUMPTION IN DESALINATION BY CAPACITIVE DEIONIZATION AND REVERSE OSMOSIS
LATEST DEVELOPMENTS AND FUTURE DIRECTIONS IN MEMBRANE DESALINATION
APPLICATION OF RENEWABLE ENERGY TECHNOLOGY FOR WATER DESALINATION
CHALLENGES SURROUNDING THE USE OF NUCLEAR TECHNOLOGY AS AN ENERGY SOURCE
CONCLUDING REMARKS
REFERENCES
Terminology
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