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We must, from the beginning, dispose of a precise number N0 of seeds. Therefore, if L is the intended size of the crystals and M is the crystals’ intended mass, then, in these conditions:
The seeds can result from:
The supersaturation over this initial period is:
Q: thermal power (W) r: vaporization heat (J. kg-1).
The crystal mass is:
At time t, the number of crystals JdT have appeared at time т and have grown over time (t - т).
J is a function of AX = X - X* with X = Ms / Me and dMs = -dMe.
The logical sequence of the calculations is as follows:
In other words:
The Runge-Kutta method of order 4 is suitable to study nucleation variations according to time (see Appendix 1).
In fact, d0/dt results in a decrease when the temperature 0 decreases (see exchanger theory). Similarly, power Q also decreases.
Figure 4.12. (1) “Natural” program; (2) controlled program
Finally, AX decreases due to the rapid increase in dMc/dt with t, so that J nucleation reaches a maximum before decreasing until AX, having a moderate value, is only of use to crystal growth.
After this instant, d(AX/dt) moves towards zero, which provides the desired values for dT/dt and Q. The т parameter, which is the instant of crystal formation, has reached limit Tlim, so that, for t > Tlim, the J nucleation is very low.
According to Figure 4.12 in the case of non-seeded nucleation, supersaturation control leads to a reduction in the spike amplitude of primary nucleation.
Similarly, crystallization after seeding leads to a variation in the neighboring supersaturation of curve (2), for which the supersaturation maximum has been weakened significantly.
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