The continuity equation for the solid-phase i can be written as
eipi = nimi is the mass of phase i per unit volume of mixture, ei is its solid volume fraction, and pi is density of phase i. Here у =< c; > is the mean velocity of the particle i. The instantaneous velocity c; is defined as the sum of the average velocity, v;, and peculiar velocity, С;,
c = v; + С; with < C >= 0
The momentum equation for phase i may be expressed as
Fluctuating Energy Equation
The fluctuating energy equation for solid-phase i can be expressed as where
0i is the granular temperature or the fluctuating granular energy of the solid-phase I,
In the above governing equations, the relevant variables describing the flow field are the average velocities, the solid volume fractions, and the granular temperatures evaluated at location r of the center of the particle at time t.
The kinetic equations that characterize the flow of a multiphase system are
where gip(r) is the spatial-pair radial distribution function when the particles i and p are in contact. A solution of Eq. (2.87) near the equilibrium was obtained using the Chapman-Enskog method (Ferziger and Kaper 1972; Chapman and Cowling 1970),
where f0 is the Maxwellian velocity distribution
and ф is a perturbation to the Maxwellian velocity distribution. It is a linear function of the first derivative of ni, di, and vi. Note that ф is function of the phase mean velocity, vi, and not the total flow velocity, because, as mentioned in the introduction, each kind of particle is treated as a separate phase and the interaction is at the interface. The radial distribution function gip(ei, ep) describes a multisized mixture of hard spheres at contact. Iddir and Arastoopour (2005) modified the Lebowitz (1964) radial distribution function. This approach is in agreement with the results of molecular dynamics (MD) simulation obtained by Alder and Wainwright (1967) at both lower and higher solid volume fractions. This equation can be written as
The expression of gpp(ei, ep) is obtained by simply interchanging the indices i andp.
For a more detailed explanation for constitutive relation expressions for all solid phases, see Iddir and Arastoopour (2005).